Hi,
This is not a DPM issue, it's Windows explorer has tighter security. You can navigate to it using Administrative command prompt, and your backup application should also have access.
C:\Program Files\Microsoft DPM\DPM\Volumes\ShadowCopy\Non VSS Datasource Writer\vol_3a4326a2-ab4d-42e9-aa9e-7ff14a20e197\0e812d75-07e3-4879-b7c5-ca372866a179\Full>dir
Volume in drive C is OSDisk
Volume Serial Number is 72E2-7F19
Directory of C:\Program Files\Microsoft DPM\DPM\Volumes\ShadowCopy\Non VSS Datasource Writer\vol_3a4326a2-ab4d-42e9-aa9e-7ff14a20e197\0e812d75-07e3-4879-b7c5-ca372866a179\Full
04/30/2013 04:27 PM <DIR> .
04/30/2013 04:27 PM <DIR> ..
10/29/2012 12:20 PM <DIR> c-Vol
05/09/2013 09:18 AM 5,272 DatasetContextInformation.xml
04/09/2013 05:32 PM <DIR> f-Vol
04/09/2013 11:01 PM <DIR> g-Vol
1 File(s) 5,272 bytes
5 Dir(s) 20,754,763,776 bytes free
C:\Program Files\Microsoft DPM\DPM\Volumes\ShadowCopy\Non VSS Datasource Writer\vol_3a4326a2-ab4d-42e9-aa9e-7ff14a20e197\0e812d75-07e3-4879-b7c5-ca372866a179\Full>