You can manage certificates through the Exchange Management Shell.
You can use the following cmdlets to manage digital certificates on an Exchange Client Access server:
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Import-ExchangeCertificate This cmdlet is used to import certificates to a server. You can import a CA-signed certificate (to complete a pending certificate signing request (CSR)) or a certificate with a private key (PKCS #12 files, generally with a .pfx extension, previously exported from a server along with the private key).
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Remove-ExchangeCertificate This cmdlet is used to remove certificates from a server.
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Enable-ExchangeCertificate This cmdlet is used to assign services to a certificate.
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Get-ExchangeCertificate This cmdlet is used to retrieve an Exchange certificate based on a variety of criteria.
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New-ExchangeCertificate This cmdlet is used to create a new self-signed certificate or a CSR.
Once you have imported the new cert make sure to enable it on the applicable services.
example: Enable-ExchangeCertificate -Thumbprint <new cert thumbprint> -Services POP,IMAP,SMTP,IIS
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