Hi RayHell,
Don't remove the old ones, you need to just assign services to the new one.
Follow this guide:
9.Now, to enable your certificate for use, go back to the Certificates section of the Exchange Admin Center, highlight the certificate you want to use and click the edit button.
10.Click the Services option on the left side.
11.Select the services for which you would like to enable your new certificate, click Save.
https://www.digicert.com/ssl-certificate-installation-microsoft-exchange-2010.htm