Hi,
According your description, you have encountered this issue: Word 2010 crashes/hangs when saving files and you might get a error "Word has stop working". It might be caused by some factor, please try the follow methods:
One:
Delete the Word Data registry key and check if youre able to save documents. The steps below would help you deleting the registry key.
1) Exit all Office programs.
2) Click Start > All Programs > Accessories > Run
3) Locate the following registry sub key:
HKEY_CURRENT_USER\Software\Microsoft \Office\14.0\Word\Data
4) ClickData, and then click Export on the File menu.
5) Name the fileWddata.reg, and then save the file to the desktop.
6) ClickDelete on the Edit menu, and then clickYes.
7) Exit Registry Editor.
8) Start Word.
Two:
Disable all the add-ons, especially send to bluetooth add-on.
Then, you can try more methods in this KB:
https://support.microsoft.com/en-us/kb/921541
If this issue still exists, we can go to collect the event log and check if there is any error logged.
Regards,
George ZhaoTechNet Community Support